Solvent-Free Synthesis Of Novel Phthalocyanines Containing Triazole Derivatives Under Microwave Irradiation


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Bodur O. , Özil M., Kahveci B.

IUPAC 2013 – 44th World Chemistry Congress, İstanbul, Turkey, 11 - 16 August 2013, vol.2, pp.1109

  • Publication Type: Conference Paper / Summary Text
  • Volume: 2
  • City: İstanbul
  • Country: Turkey
  • Page Numbers: pp.1109

Abstract

Recently, much effort has been dedicated to the microwave assisted synthesis of metal-free and metallophthalocyanines [1]. In addition, there have been several incidences reported of the synthesis of unsubstituted, and some substituted, metallophthalocyanines using microwave irradiation under solvent free conditions [2,3].

A fast and effective procedure was developed for the synthesis of bulky substituted metal-free phthalocyanines and metallophthalocyanines. The present procedure described in this paper demonstrated that microwave processing combined with solvent-free condition leads to shorter reaction time, higher yield, a clean reaction product and easier workup than classical thermal processing [4].