The synthesis, photophysical and electrochemical studies of symmetrical phthalocyanines linked thiophene substituents

ÇOĞAL S., OCAKOĞLU K., ÖKSÜZ A.

INORGANICA CHIMICA ACTA, vol.423, pp.139-144, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 423
  • Publication Date: 2014
  • Doi Number: 10.1016/j.ica.2014.08.014
  • Journal Name: INORGANICA CHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.139-144
  • Süleyman Demirel University Affiliated: Yes

Abstract

Tetrakis 4-(3-thienyl) and tetrakis 4-(5'-hexyl-2,2'-bithiophene) peripherally substituted zinc phthalocyanines were synthesized by using phthalonitrile derivatives. The phthalonitrile compounds were obtained through palladium catalyzed Suzuki-Miyaura cross-coupling reaction. The synthesized phthalocyanines were characterized by FT-IR, H-1 NMR and MALDI-TOF-MS methods. The absorption and emission properties were studied by using UV-Vis absorption and photoluminescence spectroscopies. The electrochemical behaviors of compounds were also investigated using cyclic voltammetry (CV) measurements. The 5'-hexyl-2,2'-bithiophene substituent shifted the absorption band to red region and decreased the HOMO-LUMO energy gap of phthalocyanines. (C) 2014 Elsevier B.V. All rights reserved.