An approach to the synthesis of chemically modified bisazocalix[4] arenes and their extraction properties

Tilki T., Sener I., Karci F., Gulce A., Deligoz H.

TETRAHEDRON, cilt.61, sa.40, ss.9624-9629, 2005 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61 Konu: 40
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.tet.2005.07.078
  • Dergi Adı: TETRAHEDRON
  • Sayfa Sayıları: ss.9624-9629


Bisazocalix[4]arenes [N,N'-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene)benzene (1), N,N'-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix [4] arene)biphenyl (2) and N,N'-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene)-2,2'-dinitro biphenyl (3)] have been synthesized from 25,26,27-tribenzoyloxy-28-hydroxycalix [4] arene by diazocoupling with the corresponding aromatic diamines (p-phenylenediamine, 4,4'-diamino biphenyl and 4,4'-diamino-2,2'-dinitrobiphenyl). Extraction studies of bisazocalix[4]arenes 1, 2, and 3 show no difference in their extraction behavior and selectivity, whereas azocalix[4]arenes are a poor extractant for heavy metal cations. The absorption spectra of the prepared bisazocalix[4]arenes are discussed, both the effect of varying pH and solvent upon the absorption ability of bisazocalix[4]arenes. (c) 2005 Elsevier Ltd. All rights reserved.