Thermally-exfoliated graphene Oxide/ZnO nanocomposite catalysts for photocatalytic hydrogen evolution and antibacterial activities


Tuna Genç M., Sarilmaz A., Dogan S., Aksoy Çekceoğlu İ., ÖZEN A., Aslan E., ...More

International Journal of Hydrogen Energy, vol.48, no.78, pp.30407-30419, 2023 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 48 Issue: 78
  • Publication Date: 2023
  • Doi Number: 10.1016/j.ijhydene.2023.04.185
  • Journal Name: International Journal of Hydrogen Energy
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chemical Abstracts Core, Communication Abstracts, Environment Index, INSPEC
  • Page Numbers: pp.30407-30419
  • Keywords: Antibacterial activity, Carbon nanomaterials, Graphene-derived materials, Hydrogen evolution, Nanocomposite catalyst
  • Süleyman Demirel University Affiliated: Yes

Abstract

Carbon nanomaterials are of great interest due to their enhanced charge separation in hydrogen evolution reactions. Herein, heterostructured TEGO/ZnO nanocomposite catalyst was obtained by combining 3D multilayer graphene-like nanomaterial obtained by green process from recycled carbon source with ZnO to improve photocatalytic activity. Here, photodeposition of MoSx and Pt in aqueous solution is performed on TEGO/ZnO nanocomposite to obtain TEGO/ZnO/MoSx and TEGO/ZnO/Pt by reducing (NH4)2MoS4 and H2PtCl6.6H2O, respectively. Photodeposited MoSx and Pt on TEGO/ZnO nanocomposite resulted in enhanced photocatalytic activity and stability due to increased active sites and enhanced electron transfer ability due to cocatalyst effect. In addition, antibacterial activity of TEGO/ZnO nanocomposite against Escherichia coli and Staphylococcus aureus was investigated by bacterial growth kinetic assay. This work could open up a new nanomaterial for chemical and biological applications.