Synthesis and characterization of copper(II) and nickel(II) complexes of the schiff bases derived from Δ3-Tetrahydrobenzaldehyde and 2-methyl-Δ3-tetrahydrobenzaldehyde and glycine
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.28, sa.2, ss.295-301, 1998 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 28 Sayı: 2
- Basım Tarihi: 1998
- Doi Numarası: 10.1080/00945719809351904
- Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.295-301
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
Copper(II) and nickel(II) complexes with the Schiff bases derived from Δ3-tetrahydrobenzaldehyde or 2-methyl-Δ3-tetrahydrobenzaldehyde and glycine were synthesized. These compounds have been characterized by elemental analyses, conductivity measurements and infrared spectroscopy. The Schiff base ligands and their complexes have been further characterized by 1H NMR. The results suggest that the Schiff base acts as a bidentate ligand which bonds to the metal ions through the imino nitrogen and carboxylate oxygen. The potassium salts of the Schiff bases are 1:1 electrolytes, but all the complexes are non-electrolytes.