Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)biphenyls and their complexes
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, cilt.32, sa.2, ss.109-115, 2006 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 32 Sayı: 2
- Basım Tarihi: 2006
- Doi Numarası: 10.1134/s1070328406020059
- Dergi Adı: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.109-115
- Süleyman Demirel Üniversitesi Adresli: Hayır
Özet
Three new substituted 4-(alkylaminoisonitrosoacetyl)biphenyls (ligands) derived from 4-biphenylhydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for ligands: ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl)pyridine. Mononuclear or binuclear cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), and lead(II) complexes with these ligands were synthesized. These compounds were characterized by elemental analyses, AAS, infrared spectra, and magnetic susceptibility measurements. The ligands were additionally characterized by H-1 NMR. The results suggest that the ligands act as tridentate ligands.