Petrography and Geochemistry of the Middle Jurassic–Lower Cretaceous Limestones from the Mustafakemalpaşa Quarries, Bursa, Turkey: The Depositional Environmental and Diagenetic Processes
Minerals, cilt.15, sa.11, 2025 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 15 Sayı: 11
- Basım Tarihi: 2025
- Doi Numarası: 10.3390/min15111135
- Dergi Adı: Minerals
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, ABI/INFORM, INSPEC
- Anahtar Kelimeler: element geochemistry, Inatlar limestone, Mustafakemalpaşa, paleo-redox, paleosalinity
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
Inatlar limestone, which is dated to the Middle Jurassic–Lower Cretaceous, is exposed between the villages of Kabulbaba and Söğütalan in the Mustafakemalpaşa district of Bursa, Turkey. This study investigates its mineralogical, petrographic, and geochemical characteristics, focusing on major, trace, and rare earth element (REEs) compositions to interpret the depositional environment, paleoenvironmental conditions, and diagenetic processes. Petrographic analysis identified four main limestone types: siliceous, micritic, fossiliferous, and dolomitic. REEs geochemistry indicates enrichment in heavy REEs (HREEs), depletion in light REEs (LREEs), and characteristic anomalies with negative Ce and Eu and positive La, suggesting an open marine depositional environment and early diagenesis. Trace element data point to deposition in settings ranging from continental margins to open marine environments. Ni and V concentrations reflect a spectrum of depositional conditions, including terrestrial, transitional (oxic–dysoxic), and marine anoxic settings. Z values support the theory that the limestones have a marine origin. δ13C and δ18O isotope values indicate deposition in both hydrothermal and typical marine carbonate environments. Y/Ho and Er/Nd ratios reveal the influence of terrestrial input, as well as diagenetic and detrital material. Furthermore, V/(V + Ni) ratios reflect fluctuating oxic to suboxic/anoxic conditions, while Ni/Co ratios indicate predominantly euxinic and, to a lesser extent, anoxic conditions. Altogether, these geochemical signatures suggest that the Inatlar limestone was deposited in a dynamic marine system characterized by variable redox states and salinity fluctuations.