A DINUCLEAR OXYGEN-BRIDGED SCHIFF BASE IRON(III) COMPLEX DERIVED FROM N,N'-bis(4-METHOXY-2-HYDROXYBENZYLIDENE)2,2-DIMETHYLPROPANE-1,3-DIAMINE


Karahan A., Kurtaran R., Yahsi Y., Gungor E., Kara H.

JOURNAL OF STRUCTURAL CHEMISTRY, cilt.57, ss.731-736, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 57 Konu: 4
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1134/s0022476616040156
  • Dergi Adı: JOURNAL OF STRUCTURAL CHEMISTRY
  • Sayfa Sayıları: ss.731-736

Özet

The mu-oxo-bridged Fe(III) dimer complex [{Fe(4-MeOL1)}(2)(mu-O)]center dot HOCH3, (H-2-4-MeOL1 = N,N'-bis(4-methoxy- 2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine), 1 is synthesized and characterized by single crystal X-ray diffraction. Complex 1 contains a [{Fe(4-MeOL1)}(2)(mu-O)] dimeric unit with a methanol solvent molecule of crystallization. Each Fe(III) ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Fe(III) atom is coordinated by two N and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O2- ion, linking another Fe(III) ion in the complex. There are intermolecular C-H. O and C-H....pi interactions among the dinuclear complexes.