Synthesis and complex formation of four new unsymmetrical vic-dioximes
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.22, sa.6, ss.851-861, 1992 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 22 Sayı: 6
- Basım Tarihi: 1992
- Doi Numarası: 10.1080/15533179208020249
- Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.851-861
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
Anti-p-Tolylchloroglyoxime (PTCGH2) has been synthesized by chlorination of anti-p-tolylglyoxime. The reaction of PTCGH2 with suitable aryl or arylklyamines in ethanol between -10°C and -15°C gives unsymmetrical vic-dioximes. namely, anilino-p-tolylglyoxime (APTGH2), benzilamino-p-tolylglyoxime (BAPTGH2) p-toluidino-p-tolylglyoxime (PTPTGH2), p-anisidino-p-tolyl-glyoxime (PAPTGH2). The Ni(II) and Cu(II) complexes of these ligands are square-planer while the Co(II) complexes are octahedral with water molecules as axial ligands. 1h-nmr IR and UV-VIS data are given. © 1992, Taylor & Francis Group, LLC. All rights reserved.