Synthesis of phenyl-substituted conduritol B and its mechanism of formation
HELVETICA CHIMICA ACTA, vol.90, no.11, pp.2227-2235, 2007 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 90 Issue: 11
- Publication Date: 2007
- Doi Number: 10.1002/hlca.200790231
- Journal Name: HELVETICA CHIMICA ACTA
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.2227-2235
- Süleyman Demirel University Affiliated: Yes
Abstract
The phenyl-substituted conduritol B 8 was prepared in racemic form in a five-step sequence starting from 2-phenyl-1,4-benzoquinone(10) (Scheme 1). The reaction mechanism of the key step 12b -> 13 is discussed (Scheme 2).