Synthesis of phenyl-substituted conduritol B and its mechanism of formation


Cantekin S., Caliskan R. , Sahin E., Balci M.

HELVETICA CHIMICA ACTA, cilt.90, ss.2227-2235, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 90 Konu: 11
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1002/hlca.200790231
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Sayfa Sayıları: ss.2227-2235

Özet

The phenyl-substituted conduritol B 8 was prepared in racemic form in a five-step sequence starting from 2-phenyl-1,4-benzoquinone(10) (Scheme 1). The reaction mechanism of the key step 12b -> 13 is discussed (Scheme 2).