Nutrient recovery from anaerobic digester supernatant using a fluidized-bed reactor


Kılıç M., Yılmaz T., Partal R., Şık E., Doğan Ö., KİTİŞ M., ...More

Journal of Water Process Engineering, vol.54, 2023 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 54
  • Publication Date: 2023
  • Doi Number: 10.1016/j.jwpe.2023.103950
  • Journal Name: Journal of Water Process Engineering
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, INSPEC
  • Keywords: Anaerobic digester, Fluidized-bed reactor, Nutrient recovery, Phosphorus recovery, Struvite
  • Süleyman Demirel University Affiliated: Yes

Abstract

This study investigated nutrient recovery by struvite precipitation from anaerobic digester supernatant containing nitrogen and phosphorus at high concentrations using a fluidized-bed reactor. In the first phase, hydraulic retention time (HRT) in the system was reduced from 15 min to 2.5 min at molar Mg2+/NH4+/PO43− ratio of 1.5/16.6/1. No significant differences were detected and struvite could be precipitated at high performances even at an HRT of 2.5 min. In the second stage, the impact of Mg/P molar ratio on struvite precipitation performance was evaluated at the molar ratios of 1/1, 1.5/1, 2/1 and 2.5 min HRT. The highest NH4-N and PO4-P precipitation performances were around 38 % and 99.7 %, respectively, at an Mg/P molar ratio of 2. In the last stage, the impact of volatile fatty acid presence on the system performance was investigated by adding 1000 mg/L acetate to the synthetic wastewater at an Mg/P molar ratio of 1.5/1. Observing above 99 % PO4-P removal efficiency both in the presence and absence of acetate confirmed that VFA may not have adverse impact on struvite precipitation performance. According to XRD results, struvite precipitates had a crystal structure with only a small amount of impurities.