Creating a Low-Potential Redox Polymer for Efficient Electroenzymatic CO2 Reduction

Yuan M., Sahin S. , Cai R., Abdellaoui S., Hickey D. P. , Minteer S. D. , ...Daha Fazla

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, cilt.57, sa.22, ss.6582-6586, 2018 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Konu: 22
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1002/anie.201803397
  • Dergi Adı: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  • Sayfa Sayıları: ss.6582-6586

Özet

Increasing greenhouse gas emissions have resulted in greater motivation to find novel carbon dioxide (CO2) reduction technologies, where the reduction of CO2 to valuable chemical commodities is desirable. Molybdenum-dependent,formate dehydrogenase (Mo-FDH) from Escherichia coli is a metalloenzyme that is able to interconvert formate and CO, We describe a low-potential redox polymei; synthesized by a facile method, that contains cobaltocene (grafted to poly(allylumine), Cc-PAA) to simultaneously mediate electrons to Mo-FDH and immobilize Mo-FDH at the surface of carbon electrode. The resulting bioelectrode reduces CO2 to formate with a high Faradaic efficiency of 991 +/- 5 % at a mild applied potential of -0.66 V vs. SHE.