Adsorption of trimethyl phosphite on H-KA, H-NaA, H-CaA and H-NaX zeolites: an IR study

Cicek, E; Bardakci, B; Ucun, F; Bahceli, S

doi:10.1515/zna-2003-5-611

Adsorption of trimethyl phosphite on H-KA, H-NaA, H-CaA and H-NaX zeolites: an IR study

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Cicek E., Bardakci B., Ucun F., Bahceli S.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, vol.58, pp.313-316, 2003 (SCI-Expanded)

Publication Type: Article / Article
Volume: 58
Publication Date: 2003
Doi Number: 10.1515/zna-2003-5-611
Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.313-316
Süleyman Demirel University Affiliated: No

Abstract

Infrared spectroscopy has been used in adsorption studies of trimethyl phosphite (TMP) on the hydrogen (H) form of the A-type and 13X zeolites. Infrared spectra of H-zeolites, except H-KA, show that TMP reacts rapidly with silanol hydroxyls on their surfaces and gives rise to form product molecules such as SiOCH3 and liquid dimethyl phosphite. The unaccomplished adsorption on the H-KA zeolite has been attributed to the occurence of stable KOH hydroxyls with not-exchanged K cations instead of SiOH hydroxyls on this zeolite.