Adsorption of trimethyl phosphite on H-KA, H-NaA, H-CaA and H-NaX zeolites: an IR study


Cicek E., Bardakci B., Ucun F., Bahceli S.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, cilt.58, ss.313-316, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 58
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1515/zna-2003-5-611
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
  • Sayfa Sayıları: ss.313-316

Özet

Infrared spectroscopy has been used in adsorption studies of trimethyl phosphite (TMP) on the hydrogen (H) form of the A-type and 13X zeolites. Infrared spectra of H-zeolites, except H-KA, show that TMP reacts rapidly with silanol hydroxyls on their surfaces and gives rise to form product molecules such as SiOCH3 and liquid dimethyl phosphite. The unaccomplished adsorption on the H-KA zeolite has been attributed to the occurence of stable KOH hydroxyls with not-exchanged K cations instead of SiOH hydroxyls on this zeolite.