Synthesis and complex formation of substituted aminoglyoximes of unsymmetrical vic-dioximes


SEVİNDİR H. C., EmineöZcan R. M., Ertul S., GüLer E.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.24, sa.4, ss.613-621, 1994 (Scopus)

Özet

Three new substituted aminoglyoximes, p-chloro-anilinoglyoxime (P-CAGH2), o-chloroanilinoglyoxime (0-CAGH2), m-chloroanilinoglyoxime (m-CAGH2) have been synthesized from anti -chloroqlvoxime (CPGH2) and the corresponding substituted amines. The Ni(II) and Cu(II) complexes of these ligands are square-planer while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, mass, IR spectra and elemental analyses data of the new compounds are given. © 1994, Taylor & Francis Group, LLC. All rights reserved.