Synthesis and complex formation of substituted amino-p- tolylglyoximes of unsymmetrical vic-dioximes
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.23, sa.5, ss.757-765, 1993 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 23 Sayı: 5
- Basım Tarihi: 1993
- Doi Numarası: 10.1080/15533179308016858
- Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.757-765
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
anti-p-Tolylchloroalyoxime (PTCGH2) has been synthesized by chlorination of anti-p-tolylalyoxime. The reaction of PTCGH2 with p-chloroaniline, o-chloroaniline and m-chloroaniline in ethanol between -10°C and -15°C gives unsymmetrical vic- dioximes, designated as: p-chloroanilino-p-tolylglyoxime (P-CAPTGH2), o-chloroanilino-p-tolylglyoxime (0-CAPTGH2), m- chloroanilino-p-tolylglyoxime (m-CAPTGH2). The Ni(II) and Cu(II) complexes of these ligands are proposed to be square- planer, while the Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. Structural assiguments are supported by 1H-NMR, IR and elemental analyses which are here in reported. © 1993, Taylor & Francis Group, LLC. All rights reserved.