A New Diterpenoid Alkaloid from the Roots of a White-Flowering Aconitum orientale Sample

Mericli A. H. , Cagal-Yurdusever N., ÖZÇELİK H. , Zapp J., Kiemer A. K.

HELVETICA CHIMICA ACTA, cilt.95, sa.2, ss.314-319, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 95 Konu: 2
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/hlca.201100139
  • Sayfa Sayıları: ss.314-319


From the roots of a white-flowering Aconitum orientale Miller sample, collected in Artvin-Savsat, Turkey, a new diterpenoid alkaloid named aconitorientaline (1) was isolated, along with the known diterpenoid alkaloids septentiriodine, lappaconitine, finaconitine, ranaconitine, puberanidine and delstaphinine (Fig.). The structure of 1 was established on the basis of 1H- and 13C-NMR, DEPT, 1H,1H-COSY, NOESY, HSQC, and HMBC studies. All the known compounds were identified by comparison of their 1H- and 13C-NMR data and co-TLC behavior with those of authentic samples.