Determination of force constants of planar XY3 and tetrahedral XY4 molecules by the GF matrix method


Guclu V., Ucun F.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, vol.60, no.3, pp.183-186, 2005 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 60 Issue: 3
  • Publication Date: 2005
  • Doi Number: 10.1515/zna-2005-0309
  • Title of Journal : ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
  • Page Numbers: pp.183-186

Abstract

The force constants of the internal coordinates of planar XY3 and tetrahedral XY4 molecules were calculated using the GF matrix method. The matrix solutions were carried out by means of a computer program built relative to the Newton-Raphson method, and the calculations were listed in tables. For tetrahedral XY4 molecules having the same Y atom it was found that the force constants decrease with the increasing mass of the X atom, and this was attributed to the slowing of the molecule with increasing mass of the centre X atom.