The Synthesis of new bis(amino-p-nitro-phenylglyoximes) and their polymeric complexes with Cu(II), Ni(II), and Co(II)
Journal of Macromolecular Science, Part A, cilt.32, sa.sup8, ss.1227-1235, 1995 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 32 Sayı: sup8
- Basım Tarihi: 1995
- Doi Numarası: 10.1080/10601329508020344
- Dergi Adı: Journal of Macromolecular Science, Part A
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.1227-1235
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
In this study, five new bis(amino-p-nitrophenylglyoximes), 1,4-phenylene bis(amino-p-nitrophenylglyoxime), 1, 1’ -biphenyl-4,4’-bis(amino-p-nitrophenyIgly-oxime), 1,1’- diphenyloxy-4,4’-bis(amino-p-nitrophenylglyoxime), 1, l’-diphenyl-methlene-4,4’-bis(amino-p-nitrophenylglyoxime) and 1,1 ‘-diphenylethylene-4,4’-bis(amino-p-nitrophenylglyoxime) have been synthesized from anti-p-nitrochloro-phenylglyoxime and the corresponding aromatic diamines. Their polymeric complexes with Cu(II), Ni(II) and Co(II) have been obtained. The Cu(II) and Ni(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, IR and elemental analyses data of the complexes and ligands are given. © 1995, Taylor & Francis Group, LLC. All rights reserved.