Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

Merdivan, M; Karipcin, F; Kulcu, N; Aygun, RS

doi:10.1023/a:1010140125400

Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

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Merdivan M., Karipcin F., Kulcu N., Aygun R.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, vol.58, no.3, pp.551-557, 1999 (Journal Indexed in SCI)

Publication Type: Article / Article
Volume: 58 Issue: 3
Publication Date: 1999
Doi Number: 10.1023/a:1010140125400
Title of Journal : JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Page Numbers: pp.551-557

Abstract

The thermal decompositions of the complexes of N,N-dialkyl-N'-benzoylthioureas with Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III) were studied by TG and DTA techniques. These metal complexes decompose in two stages: elimination of dialkylbenzamide, and total decomposition to metal sulphides or metals. The influence of the alkyl substituents in these benzoylthiourea chelates on the thermal behaviour of the metal complexes was investigated.