Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

Merdivan, M; Karipcin, F; Kulcu, N; Aygun, RS

doi:10.1023/a:1010140125400

Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

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Merdivan M., Karipcin F., Kulcu N., Aygun R.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, vol.58, no.3, pp.551-557, 1999 (SCI-Expanded)

Publication Type: Article / Article
Volume: 58 Issue: 3
Publication Date: 1999
Doi Number: 10.1023/a:1010140125400
Journal Name: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.551-557
Süleyman Demirel University Affiliated: No

Abstract

The thermal decompositions of the complexes of N,N-dialkyl-N'-benzoylthioureas with Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III) were studied by TG and DTA techniques. These metal complexes decompose in two stages: elimination of dialkylbenzamide, and total decomposition to metal sulphides or metals. The influence of the alkyl substituents in these benzoylthiourea chelates on the thermal behaviour of the metal complexes was investigated.