Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

Merdivan, M; Karipcin, F; Kulcu, N; Aygun, RS

doi:10.1023/a:1010140125400

Study of the thermal decompositions on N,N-dialkyl-N '-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III)

Atıf İçin Kopyala

Merdivan M., Karipcin F., Kulcu N., Aygun R.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.58, ss.551-557, 1999 (SCI İndekslerine Giren Dergi)

Cilt numarası: 58 Konu: 3
Basım Tarihi: 1999
Doi Numarası: 10.1023/a:1010140125400
Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Sayfa Sayıları: ss.551-557

Özet

The thermal decompositions of the complexes of N,N-dialkyl-N'-benzoylthioureas with Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III) were studied by TG and DTA techniques. These metal complexes decompose in two stages: elimination of dialkylbenzamide, and total decomposition to metal sulphides or metals. The influence of the alkyl substituents in these benzoylthiourea chelates on the thermal behaviour of the metal complexes was investigated.