ENZYMATIC ACTIVITIES OF A NOVEL DINUCLEAR Cu(II)-Ni(II) COMPLEX: DESIGN, SYNTHESIS AND CHARACTERIZATION
FRESENIUS ENVIRONMENTAL BULLETIN, cilt.27, sa.6, ss.3958-3964, 2018 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 27 Sayı: 6
- Basım Tarihi: 2018
- Dergi Adı: FRESENIUS ENVIRONMENTAL BULLETIN
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.3958-3964
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
A novel heterodinuclear Cu(II)-Ni(II) complex of iminooxime ligand has been prepared by employing several steps. The characterization and nature of bonding of the complex have been deduced from elemental analysis, ICP-OES, FT-IR, molar conductivity, magnetic moment measurements and thermal analysis. Elemental analyses, stoichiometric and spectroscopic data of the metal complex indicated that the metal:ligand ratio of the dinuclear Cu(II)-Ni(II) complex have been found to be 2:1. The complex has been tested for enzymatic activity. Kinetic studies have been revealed that the complex exhibited high catecholase-like activity with Michaelis binding constant (K-M=1.9x10(-3)M) and the turnover number (k(cat)=339 h(-1)).