The synthesis of three new bis(amino-r-glyoximes) and their polymeric metal complexes
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.24, sa.9, ss.1461-1469, 1994 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 24 Sayı: 9
- Basım Tarihi: 1994
- Doi Numarası: 10.1080/00945719408002573
- Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.1461-1469
- Süleyman Demirel Üniversitesi Adresli: Evet
Özet
In this study, three new unsymmetrical vic-dioximes, 1,2-phenylenebis(aminoglyoxime) L1-H2, 1,2-phenylenebis(amino-phenylglyoxime) l2h2 and 1,2-phenylenebis(amino-p-tolyl-glyoxime) l3h2 have been synthesized from anti-chloroglyoxime (CGH2), anti-phenylchloroglyoxime (PCGH2) and anti-p-tolyl-chloroglyoxime (PTCGH2), and aromatic diamines. Their polymeric complexes with Ni(II), Cu(II) and Co(II) have been obtained. The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1h NMR and IR spectra and elemental analyses data are given. © 1994, Taylor & Francis Group, LLC. All rights reserved.