Palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura reactions using naphthalenomethyl-substituted imidazolidin-2-ylidene ligands in aqueous media


AKTAŞ A., Akkoc S. , GÖK Y.

JOURNAL OF COORDINATION CHEMISTRY, vol.66, no.16, pp.2901-2909, 2013 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 66 Issue: 16
  • Publication Date: 2013
  • Doi Number: 10.1080/00958972.2013.819092
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.2901-2909

Abstract

Naphthalenomethyl-substituted imidazolidinium salts (1a-g) were prepared and characterized by conventional spectroscopic methods, H-1 NMR, C-13 NMR, FTIR, and elemental analysis techniques. The in situ prepared three component systems naphthalenomethyl-substituted imidazolidinium salts, Pd(OAc)(2), and K2CO3 catalyzed quantitatively the Mizoroki-Heck and Suzuki-Miyaura coupling of aryl halides under mild conditions in aqueous media.